![]() Notice that this is not the only formula for calculating the formal charge, however, I figured it was the best variation acceptable to my students. We know from the previous post, that the formal charge can be calculated by this formula: The second approach is to use the formula for the formal charge and determine the number of lone pairs just like solving an equation with one unknown. Therefore, the correct Lewis structure would be as follows:Ī Formula to Determine the Number of Lone Pairs This combination satisfies the octet rule without a formal charge. And according to the table, the oxygen should have two lone pairs of electrons when bonded to two atoms. The following table summarizes these patterns addressing the common bonding and formal charge combinations:ĭepending on how long you have been studying organic chemistry, it may be easy for you to recognize that the oxygen needs two lone pairs to satisfy the octet rule. The first one, which is also what you should eventually aim for, is to learn the common bonding patterns of the elements in the second row and recognize the number of lone pairs and formal charges based on those. In general, there are two approaches you can use to determine the number of lone pairs. For example, how many lone pairs does the oxygen have in the following molecule? While determining this is extensively covered in the Lewis structures and VSEPR theory, it may get tricky when formal charges need to be considered as well. ![]() ![]() Today, we will focus on the number of lone pairs of electrons. ![]() In the previous post, we talked about the standard valences and formal charges in organic chemistry. ![]()
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9/1/2023 0 Comments Alfred batman![]() ![]() Julia, described as an intelligent, strong-willed teenager who is eager to succeed, will be a pivotal player in the show’s future. Many of these stories come to light during Untold Legend of the Batman #2.What’s the future of Game of Thrones? Julia, Alfred Pennyworth’s daughter, will be introduced in the seventh episode of the first season of Batman, according to Deadline. Clearly, with no parents to look up to and Alfred being his only mentor and role model, Bruce inherited his butler pal’s warrior spirit. Most of the action this guy saw was even before Bruce Wayne was even born. He even worked as an undercover spy for the west against the Germans in World War II and then against the soviets during the Cold war. He was also a part of the special forces. But no matter how the story is spun, Alfred always comes out as a war hero. He quickly makes a fist and strikes at Ra’s Al Ghul’s groin, knocking him cold in one punch.Īlso Read: REVIEW: Batman – Soul Of The Dragon His Military TalesĪlfred Pennyworth has had a myriad of origin stories within the DC Universe. Pennyworth is not one to not consider playing dirty. The mistake Ra’s Al Ghul makes is leaving Alfred’s hands free. He takes Alfred as hostage o keep Nightwing from capturing him. That was the same mistake Ra’s Al Ghul, leader of the League of Assassins did in Detective Comics #838. The bat-Family rogues have a tendency to target Alfred because they think he is a soft target. Many times, the enemies of Batman think that the quickest way to get the better of the Dark Knight is by striking where it hurts. The real Batman came soon after to save the day but Alfred’s actions did not go unnoticed. When that plan failed, he donned the Bat Suit in an attempt to heroically distract Gotham long enough for the people to be evacuated. Alfred first tried subduing the rogue meta human with the Batmobile. One such moment came when Gotham, a meta human with the same powers of Superman, was going on a rampage. But how would you react to the statement that Alfred Pennyworth has also donned the suit on numerous occasions. From Jim Gordon to Dick Grayson, the list goes on and on. Many other people have also taken up the mantle. Impersonated Batman To Fight a Superman Knockoffīruce Wayne is not the only Batman of Gotham City. ![]() The Blunderbuss does not exactly kill the Predator but it buys enough time for Batman to get back on his feet and take down the Predator with a baseball bat. That is when Alfred Pennyworth jumps in with a blunderbuss musket to level the playing field. it looks like game over for the Dark Knight. Batman is finally pinned down under a giant penny. the final showdown happens in the Bat Cave. The galaxy’s greatest hunter sets his sights on the Caped Crusader. And the story went exactly how you thought it might. DC teamed up with the Predator universe to give us Batman vs Predator. The earlier decades gave us some pretty unique crossover events. An older Alfred Pennyworth takes down a younger Bruce Wayne in his mental and physical prime. When Bruce and Alfred enter into a violent altercation, Alfred proves Bruce knows nothing about real life combat and shows him how its done. This version of Alfred has a prosthetic leg and does not mind speaking harshly to Bruce. He was an old war buddy of Thomas Wayne’s who visits the orphaned son after the Waynes are gunned down. Alfred Pennyworth of this universe is not exactly his butler. Bruce is only starting to learn the physical and mental strain it takes to keep up playing vigilante every night in Gotham City. In the alternate reality version of Batman: Earth One, the story of Bruce Wayne takes a grittier turn. You May Also Like: 4 ways HBO Max Can Revive Batman The Animated Series Showed A Young Bruce Wayne Who’s Boss Bane couldn’t help but wonder whether its Alfred Bruce inherits his combat prowess from. With swift and clean strikes, an entire vampire horde is taken down by one single man. Bane watches in awe as the former butler makes short work of the entire horde. A short while later, the duo encounter a horde of blood suckers. Alfred manages to escape after forging an alliance with Bane. Singlehandedly Killed A Horde Of VampiresĪ series of unfortunate events lead to Alfred Pennyworth becoming an inmate of the Arkham Asylum. This is a vengeful act that would have made Frank castle proud. Alfred just keeps firing at him with inhuman rage. the Batman Who Laughs #7 shows the grisly parallel reality Dark Knight try to goad Alfred into submission. But it is always special when you get to meet an alternate reality being who is a blend of two people he loves and hates the most. he holds an exceptionally strong grudge against the Joker, who targets him frequently for his schemes. ![]() |
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